| Soifon | Defeat her in the Story Mode |
| Yachiru Kusajishi | Defeat her in the Story Mode |
| Shuhei Hisagi | Defeat him in the Story Mode |
| Iduru Kira | Defeat him in the Story Mode, in the stage where he and Rangiku are both opponents |
| Rangiku Matsumoto | Defeat her in the Story Mode, in the stage where she and Iduru are both opponents |
| Rukia Kuchiki | Defeat the first part of the Story Mode |
| Shibata, Goteitaishi, Shrieker, Menos-Grande, Grandfisher, Tsukaima, Kyugohanin | Complete Story Modes A to D with 100% completion (any difficulty) |
| Don Kanonji, Ririn, Tatsuki, Aizen Sousuke, Ogihci | Complete Story Part C with 100% |
| Ichimaru Gin, Kukaku | Complete Story Part B with 100% |
| Tosen, Ururu | Complete Story Part A with 100% |
Lords of Legend RPG 
